Ah, That file is supposed to be use with D2SE, I thought you are using one, I suggest you give it a try, it's a fantastic tools for playing mods!
And about patch_d2.mpq if you decide to use D2SE, you can grab it in CORES folder if not then try Resurgence launcher, it'll download the original patch_d2.mpq as a backup file, just rename the file and you're done.
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